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內容簡介: |
《高分子物理:“结构与性能”背后的概念英文版.原书第3版》对高分子物理的多个领域作了生动而详细的介绍,内容涵盖链构象,高分子溶液,共混物和嵌段共聚物,半晶态聚合物,聚合物网络,聚合物流体等多种体系。作者还使用了大量的数学处理与实验结果,对提出的机理与数学模型进行示例与验证,勾勒出一幅浓墨重彩的高分子物理画卷。
《高分子物理:“结构与性能”背后的概念英文版.原书第3版》可作为化学化工、材料科学和物理学等专业的本科生和研究生教材,也可供有关领域的专家、学者阅读参考。
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目錄:
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出版说明
推荐序
preface(前言)
preface to the first edition第1版前言
1constitution and architecture of chains链的组成与构造1
2single chain conformations 单链构象15
2.1rotational isomeric states 旋转异构态15
2.2helices螺旋19
2.3coils 线团22
2.3.1the ideal chain理想链26
2.3.2the expanded chain膨胀链45
2.4the persistent chain持续链55
2.5the ising chain 伊辛链59
3polymer solutions 聚合物溶液69
3.1dilute and semidilute solutions稀溶液与半稀溶液70
3.1.1osmotic pressure渗透压71
3.2screening of excluded volume forces排除体积力的屏蔽82
3.3polyelectrolyte solutions聚电解质溶液89
3.3.1condensation and screening of charges 电荷的团聚与屏蔽89
3.3.2chain stretching, salt effects and interchain
ordering链伸展、盐效应与链间序95
3.3.3osmotic pressure渗透压100
4polymer blends and block copolymers共混物与嵌段共聚物105
4.1the flory?huggins treatment of polymer
mixtures聚合物混合物的flory?huggins处理方法106
4.1.1phase diagrams: upper and lower miscibility
gap相图:上临界与下临界混溶间隙117
4.2phase separation mechanisms相分离机理122
4.3critical fluctuations and spinodal
decomposition临界涨落与旋节线分解129
4.3.1critical scattering临界散射132
4.3.2decomposition kinetics分解动力学143
4.4block copolymer phases嵌段共聚物的相结构151
4.4.1layered structures层状结构155
4.4.2pretransitional phenomena前转变现象157
5the semicrystalline state半结晶态165
5.1structure characteristics结构特征167
5.1.1morphological elements 基本形态167
5.1.2structure parameters结构参数173
5.2kinetics of crystallization and melting结晶与熔融动力学181
5.3laws for the structure development结构变化规律190
5.3.1the multistage model多阶段模型199
5.4mechanisms of secondary crystallization二级结晶机理205
5.4.1the insertion mode插层模式208
5.4.2surface crystallization and melting表面结晶与熔融212
5.5crystallization from oriented melts取向熔体结晶216
6mechanical and dielectric response力学与介电响应223
6.1response functions响应函数224
6.1.1viscoelasticity粘弹性224
6.1.2orientational polarization取向极化228
6.1.3general relationships通用公式229
contents6.2relaxatory modes松弛模式236
6.2.1single?time relaxation process单时间松弛过程237
6.2.2retardation and relaxation time spectra推迟与松弛时间242
6.3specific relaxation processes and flow behavior具体松弛过程与流动行为
245
6.3.1local processes局部过程246
6.3.2glass?rubber transition and melt flow玻璃?橡胶转变与熔体流动250
6.3.3the glass transition temperature玻璃化转变温度269
6.3.4relaxation in partially crystalline systems半晶体系中的松弛277
7conjugated polymers共轭聚合物287
7.1electrooptic activity光电活性289
7.1.1excitons and free charges激发与自由电荷289
7.1.2electroluminescence电发光297
7.2effects of doping掺杂效应302
7.2.1electrical conductivity电导率302
7.2.2magnetism and reflectivity磁性与反射率306
8microscopic dynamics微观运动学313
8.1the fluctuation?dissipation theorem涨落?耗散原理313
8.2the rouse modelrouse模型317
8.2.1stress relaxation应力松弛325
8.2.2the dielectric normal mode 介电基准模式330
8.3entanglement effects in polymer melts聚合物熔体中的缠结效应333
8.3.1the reptation model爬行模型338
8.4solution viscosities溶液粘度 343
8.4.1neutral polymers: hydrodynamic
interaction中性聚合物:流体力学作用344
8.4.2polyelectrolytes: coulomb interaction聚电解质:静电作用 352
9non?linear mechanics 非线性力学357
9.1rubber elasticity橡胶弹性361
9.1.1the fixed junction model of ideal rubbers理想橡胶的固定结点模型364
9.1.2the cauchy strain tensor cauchy应变张量371
9.1.3finger?s constitutive equation finger本构方程376
9.2swelling of neutral and electrolytic gels中性与电解质凝胶的溶胀384
9.3non?newtonian melt flow非牛顿熔体的流动390
9.3.1rheological material functions 流变材料函数391
9.3.2the lodge liquid lodge液体398
9.3.3the stress?optical rule应力?光学规则404
10deformation, yielding and fracture形变、屈服与断裂415
10.1shear deformation in semicrystalline
polymers半晶聚合物中的剪切形变418
10.1.1critical strains临界应变418
10.1.2constituents of the drawing stress拉伸应力的成分426
10.1.3the mechanics of neck formation细颈形成机理429
10.1.4fibrillar state of order纤维化有序态435
10.2crazing银纹 444
10.3brittle fracture脆性断裂450
10.3.1linear fracture mechanics 线性断裂力学453
10.3.2the slow mode of crack growth裂缝生长的缓慢模式455
ascattering experiments散射实验463
a.1fundamentals基本概念463
a.1.1basic equations基本方程464
a.1.2time?resolved scattering experiments时间分解的散射实验468
a.2absolute intensities绝对强度471
a.3low angle scattering properties小角散射性质474
a.3.1guinier?s law guinier公式474
a.3.2forward scattering前散射476
a.4special polymer systems特种聚合物体系477
a.4.1binary mixtures and block copolymers二元混合物与嵌段共聚物477
a.4.2two?phase layer systems两相层状体系484
bglossary of symbols术语与符号493
cbibliography参考书目501
references参考文献505
index索引
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